A twostage direct liquefaction process is designed to give distillate products via two reactor stages in series. The primary function of the first stage is coal dissolution and is operated either without a catalyst or with only a lowactivity disposable catalyst. The heavy coal liquids produced in this way are hydrotreated in the second stage ...
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The purpose of coal conversion is the production of alternative fuels, including motor fuels, or the generation of a range of chemicals from coal by process routes, such as gasification, direct and indirect liquefaction, hydropyrolysis, and plasmapyrolysis. The application of these techniques is essential if the large reserves of coal are to be ...
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Influence of coal properties on coal conversion processescoal carbonization, carbon fiber . 123 Table 5 Coal parameters with significant influence on liquefaction process
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This indirect coal liquefaction process was analysed to provide a preliminary assessment of its economic feasibility in Australia. Analysis was enabled through Aspen Plus simulation of coal preparation, gasification, syngas conditioning, FischerTropsch (FT) synthesis and syncrude refining processes.
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However, similar to other coal liquefaction processes, the DCL process has not been widely commercialized mainly because of economic uncertainty, high CO 2 emission, and high capital cost [1,2].
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This chapter presents an assessment of the technologies that have evolved for the gasification of coal with a description of the current state of the art of the various technologies. Various types of coal are available such as lignite, subbituminous coal, bituminous coal, and anthracite. The gasification process involves two distinct stages ...
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1. Introduction. Direct coal liquefaction is the technology of catalytic converting coal to clean liquid fuel through hydrocracking the polycyclic aromatic hydrocarbons in coal to small aliphatic molecules [1].It can effectively reduce the emission of industrial waste and toxic gases as well as improving the coal utilization, thereby, showing great potential for sustainable development of coal ...
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All direct coal liquefaction methods, such as HCoal, SolventRefined Coal, and Exxon Donor Solvent processes, are alike in one principal point: coal is thermally solubilized with certain solvents, usually coalderived, with or without catalysts. If heated in a proper liquid for a short time, most of the coal dissolves.
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Request PDF | Novel Use of Residue From Direct Coal Liquefaction Process | Direct coal liquefaction residue (DCLR) is, commonly, designed to be used as a feed stock for gasification or combustion.
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The direct coal liquefaction process usually produces a liquefaction residue of about 30% of its coal feed. The effective utilization of the coal liquefaction residue (CLR), which contains about ...
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liquefaction in the early 1900s. In 1925, Franz Fischer and Hans Tropsch used an indirect liquefaction process, which still bears their name, to produce excellent transportation fuels. Germany had 25 liquefaction plants that, at their peak in 1944, produced more than 124,000 barrels daily and met 90 percent of the nation's needs.
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Direct coal liquefaction (DCL) commonly refers to catalytic hydrogenation of coal in a recycled oil solvent at high pressures with a catalyst. While a range of process configurations have been proposed, the most common version involves at least two high pressure slurry reactors in a series using a dispersed ironbased catalyst and hydrogen ...
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Coal liquefaction is one source, backed by large recoverable coal reserves globally. Significant coal liquefaction research and development (RD) was started up in the early 1970s, particularly in the USA, the UK and Japan, in response to various oil price shocks.
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Typical liquefaction process is performed at 400 °C for 60 min under 5 MPa H 2 (initial pressure) in 2:1 (solvent: coal) tetralin solvent with 5% FeS + S (an equimolar mixture of FeS and S) as catalyst. A detailed procedure of hydroliquefaction and separation can be seen elsewhere [31]. The AS and PA obtained by a batch liquefaction were ...
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Direct coal liquefaction residue (DCLR) is a byproduct of coaltoliquid technology when raw coal is converted into liquid fuel, which is harmful to the ecological environment and human can be developed into a road asphalt modifier via different techniques, that can improve and enhance asphalt performance. In this paper, the global research status of DCLR in asphalt pavement is ...
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Direct coal liquefaction (DCL) The conversion of coal to liquids via dissolution and/or hydroprocessing, without first gasifying the coal DOE United States Department of Energy FischerTropsch reaction The catalytic conversion of synthesis gas to primarily hydrocarbons, the discovery being credited to Franz Fischer and Hans Tropsch
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The effective utilization of the coal liquefaction residue (CLR), which contains about 80% organic matter, is of great significancefor improving the oil yield of the direct liquefaction...
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Coal liquefaction is a process that converts coal into hydrocarbon products. Most often, the major products are condensed aromatic liquid s, with some gases and solids also produced, pending on operating conditions and the type of coal and process used. Liquefaction is accomplished by
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Bergius treated a mixture of pulverized bituminous coal and coalderived heavy oil with hydrogen, at high temperature and pressure, to give a liquid product consisting of heavy oils, middle distillates, gasoline, and gases. Various metal compounds have been used to catalyze the process.
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were ever built or operated for direct coal liquefaction. It was reported that the four major operating coal liquefaction pilot plants in the US all experienced problems including severe equipment The commercial Shenhua plant will be a significant step in determining the viability of the direct liquefaction process route.
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As a country that is poor in petroleum yet rich in coal, it is significant for China to develop direct coal liquefaction (DCL) technology to relieve the pressure from petroleum shortages to guarantee national energy security. To improve the efficiency of the direct coal liquefaction process, scientists and researchers have made great contributions to studying and developing highly efficient ...
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synthetic coalbased oil process with indirect coal liquefaction technology and a synthetic ammonia process (Xie et al. 2010). The primary steps include pressurized gasication to produce synthesis gas (or syngas), gas purication, FischerTropsch (FT) synthesis to produce dierent liquid fuels and oil processing (Xie et al. 2010).
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also routes for direct conversion of coal into liquids (, direct coal liquefaction [DL]) involving reaction of coal at high pressures and temperatures with hydrogen (H 2 ) in the presence of solvents and catalysts, yielding synthetic crude oil that can be refined into liquid fuels.
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This COconversion process generates CO 2, which is captured before it is released via an adsorption process at a purity as high as 90%. The other route is the power and steam consumption for ICLs. The generation of power and steam via coal combustion leads to carbon emissions with CO 2 concentrations in the range of 10~20% in the exhaust gas.
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The chemical constituents present in coal structure impact greatly on its mechanical behavior. The composition of organic matter and its degree of decomposition led to varying coal strength and modulus of elasticity of different coals (Pan et al. 2013; Singh and Mrityunjay 2018b; Ahamed et al. 2019) as the chemical structure was of low rank have a high concentration of aliphatic ...
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A material supplier from Belgium would like to produce limestone powder for his custome...
India is rich in various mineral resources and it is an important mineral processing market
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